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PVDC Coextruded Film

PVDC high barrier film was introduced in the late 1930s, initially used during World War II for moisture and oxidation protection of military supplies and equipment; it was later widely used for packaging pharmaceuticals, food, chemicals, and electronic devices. As food packaging, PVDC high barrier film helps preserve freshness, maintain aroma, and extend shelf life.


Product Introduction

  Introduction to PVDC High Barrier Film

  PVDC high barrier film was introduced in the late 1930s. Its early use was for moisture and oxidation protection packaging of military supplies during World War II; later it was widely used for packaging pharmaceuticals, food, chemicals, and electronic devices. As food packaging, PVDC high barrier film helps preserve freshness, aroma, and extends shelf life.

  PVDC high barrier film is currently the high barrier transparent material certified by the US FDA for food contact. It is widely used for freshness preservation and odor isolation in pharmaceuticals, food, cigarettes, tea, and beverages, as well as moisture-proof packaging for chemical, electronic, and military products, including shrink packaging, non-shrink packaging, and rigid packaging.

 

  Advantages of PVDC High Barrier Film

  1. PVDC is abundant and an energy-saving product.

  The raw material of PVDC high barrier film is a copolymer, with 66% of the main raw material derived from sea salt, a component enriched in the ocean; the remaining 34% comes from petroleum or coal, whereas ordinary plastics are 100% petroleum-based. Additionally, during production, it undergoes water dispersion and emulsion polymerization without secondary pollution.

  2. Material-saving and less waste.

  In PVDC high barrier film, a 5% PVDC layer can extend the shelf life of meat products to 6 months to one year, and grains to 3 to 5 years; compared to plastic packaging, its protective function can save 700 times more than BOPP; thus achieving material reduction and reducing waste at the source.

  3. Excellent application performance; shelf life equals value.

  PVDC high barrier film can keep pharmaceuticals and food from deteriorating within their shelf life, preventing large amounts of moldy products from becoming waste and harming the environment; the extended shelf life plays an important role in buffering or regulating the market and protecting product circulation.

  4. High environmental friendliness

  In the United States, PVDC high barrier film is recognized as a non-toxic, safe plastic material, certified by the FDA for food packaging; in Germany, PVDC packaging is classified as green packaging and holds the Green Dot mark; in Japan, it has been confirmed that incinerating PVDC products does not affect dioxin emissions.

 

  PVDC high barrier film is a polymer copolymer. Compared with other films, it has better transparency, printability (can be printed inside to prevent packaging abrasion and color loss), chemical resistance, toughness, higher impact strength, good heat shrinkability and chemical stability, and can be heat-sealed at low temperatures. Due to its high crystallinity, it features excellent comprehensive barrier properties. Because polyvinylidene chloride resin contains no hydrophilic groups, the product can effectively block water vapor transmission, and its gas barrier properties are not affected by environmental temperature and humidity.

  Besides the general properties of plastic products, PVDC high barrier film also has excellent self-extinguishing, oil resistance, flavor retention, and excellent moisture-proof and mildew-proof properties; it provides excellent protection for the color, aroma, and taste of food, can multiply the freshness and preservation period of food, and greatly reduce food spoilage caused by seasonal changes and other factors.

  Therefore, PVDC high barrier film plays an important role in improving enterprise packaging quality.

 

  Comparison Chart of Oxygen Barrier between PVDC High Barrier Film and EVOH Coextruded Film

 Comparison Chart of Oxygen Barrier between PVDC High Barrier Film and EVOH Coextruded Film

 

  Comparison of Barrier Properties between PVDC High Barrier Film and Other Packaging Films

 

Polymer

Oxygen

Water Vapor

Carbon Dioxide

Nitrogen

PVDC (MA copolymer)

0.5-6

0.1-0.3

0.1-0.5

0.1-0.5

PVDC (VC copolymer)

43931

0.4-1.0

0.3-0.7

0.1-0.8

PA6

35

93-155

43-59

 

PP

300

3.6-10.2

1200

60

PET

74-138

27.4-46.7

35-50

44189

PVC

77-310

13.2-71.3

140-400

 

LDPE

500-700

15.2-23.4

2000-4000

200-400

HDPE

200-500

3.5-11.1

2000-4000

15-300

PS

600-800

10.5-33.6

2000-4000

40-50

PAN

11.6

31.0-47.2

6

 

EVOH

0.2

47

0.9

0.02

(32% Ethylene)

EVOH

1.8

95

1.4

0.13

(44% Ethylene)

 

  Note: Film thickness 25.4um; gas permeability unit cm³/m²*24h*0.1MPa, 50% RH; water vapor permeability unit: g/cm³*24h, 100% RH

 

  The table shows that PVDC has excellent barrier properties, exhibiting very high resistance to oxygen, nitrogen, carbon dioxide, and water vapor; compared to other materials, its barrier performance is several to even hundreds of times better.

  The figure shows that the barrier performance of PVDC high-barrier film does not change with environmental humidity. Even in high humidity environments such as southern rainy seasons, it still maintains its high barrier properties.

 

  (MA type) PVDC Coextruded Film Test Analysis Report

 

  1. Performance Comparison of Several Films (Oxygen Permeability Unit: cm3/(m2·24h·0.1Mpa), Water Vapor Permeability (g/㎡·24h))

 

Film
Type

Oxygen Permeability

Water Vapor Permeability

Formability

Transparency

High Temperature Resistance
Resistance

Adhesion
Body
Property

Flexibility
Softness
Degree

Prevention of
Discoloration
Ability

Oil Resistance

Fragrance Retention

Chemical Resistance

Protection

Before Boiling

After Boiling

Before Boiling

After Boiling

(MA type) PVDC
Coextruded Film

0.8-8

Unchanged

0.8-2

Unchanged

Excellent

Excellent

100℃

Excellent

Excellent

Excellent

Good

Excellent

Excellent

Excellent

(VC type) PVDC
Composite Film

4-50

Unchanged

1-6

Unchanged

Good

Good

121℃

Good

Good

Good

Good

Good

Good

Good

EVOH
Coextruded Film

0.2-1.8

Greater than 1000

20-70

Excellent

Excellent

100℃

Excellent

Average

Excellent

Poor

Good

Good

Good

 

  2. Partial Performance Comparison of Several Films

 

 

(VC type) PVDC Composite Film

(MA type) PVDC Coextruded Film

EVOH Coextruded Film

Cover Film

Base Film

Cover Film

Base Film

Cover Film

Base Film

Tensile Strength, N

Longitudinal

67

52

62.5

57.65

76

109

Transverse

125.5

52

107.5

47

72

107

Nominal Strain at Break, %

Longitudinal

154.5

154.5

197

630.5

86

553

Transverse

46

123.5

34.5

735

83

593

 

(VC type) PVDC Composite Film

(MA type) PVDC Coextruded Film

Untreated

Treated

Untreated

Treated

Untreated

Treated

Cover Film
(VC type) PVDC Composite Film

Base Film
EVOH Coextruded Film

Cover Film (VC type) PVDC Composite Film

Base Film
EVOH Coextruded Film

Cover Film

Base Film

Cover Film

Base Film

Cover Film

Base Film

Cover Film

Base Film

Oxygen Permeability
cm3/(m2·24h·0.1Mpa

14.017

16.89

13.186

12.990

5.249

6.328

4.294

4.468

14.745

1.858

13.464

2.219

Water Vapor Permeability
g/㎡·24h

1.308

1.436

1.408

1.365

1.296

1.449

1.114

1.212

1.702

2.244

1.826

2.482

 

  From the above two comparison tables, it can be seen that compared with the common (VC type) PVDC composite stretch film and EVOH coextruded film, the (MA type) PVDC coextruded film has advantages such as high barrier, high transparency, softness, body adhesion, easy tearing, and easy stretch forming. Compared with EVOH coextruded film, its barrier property does not change with environmental temperature and humidity, whereas EVOH coextruded film’s barrier property decreases by hundreds of times under high temperature and high humidity conditions, losing its barrier function; the (MA type) PVDC coextruded film provides excellent protection for the color, fragrance, and taste of food, can multiply extend the freshness and shelf life of food, and significantly reduce food spoilage caused by seasonal changes and other factors.

Keywords: Masterbatch

PVDC Coextruded Film

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