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High barrier PVDC blister film

PVDC high barrier film was introduced in the late 1930s, initially used during World War II for moisture and oxidation protection of military supplies and equipment; it was later widely used for packaging pharmaceuticals, food, chemicals, and electronic devices. As food packaging, PVDC high barrier film helps preserve freshness, maintain aroma, and extend shelf life.


Product Introduction

  Introduction to PVDC High Barrier Film

  PVDC high barrier film was introduced in the late 1930s. Its early use was for moisture and oxidation protection packaging of military supplies during World War II; later it was widely used for packaging pharmaceuticals, food, chemicals, and electronic devices. As food packaging, PVDC high barrier film helps preserve freshness, aroma, and extends shelf life.

  PVDC high barrier film is currently the high barrier transparent material certified by the US FDA for food contact. It is widely used for freshness preservation and odor isolation in pharmaceuticals, food, cigarettes, tea, and beverages, as well as moisture-proof packaging for chemical, electronic, and military products, including shrink packaging, non-shrink packaging, and rigid packaging.

 

  Advantages of PVDC High Barrier Film

  1. PVDC is abundant and an energy-saving product.

  The raw material of PVDC high barrier film is a copolymer, with 66% of the main raw material derived from sea salt, a component enriched in the ocean; the remaining 34% comes from petroleum or coal, whereas ordinary plastics are 100% petroleum-based. Additionally, the production process involves water dispersion and emulsion polymerization without secondary pollution.

  2. Material-saving and less waste.

  In PVDC high barrier film, a 5% PVDC layer can extend the shelf life of meat products to 6 months to 1 year, and grains to 3 to 5 years; compared to plastic packaging, its protective function can save 700 times more than BOPP; thus achieving packaging material reduction and reducing waste at the source.

  3. Excellent application performance; shelf life equals value.

  PVDC high barrier film can keep pharmaceuticals and food from deteriorating within their shelf life, preventing large amounts of moldy products from becoming waste and harming the environment; the extended shelf life plays an important role in buffering or regulating the market and protecting product circulation.

  4. High environmental friendliness

  In the United States, PVDC high barrier film is recognized as a non-toxic, safe plastic material, certified by the FDA for food packaging; in Germany, PVDC packaging is included in green packaging and holds the Green Dot mark; in Japan, it has been confirmed that incinerating PVDC products does not affect the amount of dioxins produced.

 

  PVDC high barrier film is a polymer copolymer. Compared with other films, PVDC high barrier film has better transparency, printability (can be printed inside to prevent packaging abrasion and color fading), chemical resistance, toughness, higher impact strength, good heat shrinkability and chemical stability, and can be heat-sealed at low temperatures. Due to its high crystallinity, it features excellent comprehensive barrier properties. Because polyvinylidene chloride resin contains no hydrophilic groups, the product can effectively block water vapor transmission, and its gas barrier properties are not affected by environmental temperature and humidity.

  In addition to the general properties of plastic products, PVDC high barrier film also has excellent self-extinguishing, oil resistance, flavor retention, and excellent moisture-proof and mildew-proof properties; it provides excellent protection for the color, aroma, and taste of food, can multiply the freshness and preservation period of food, and significantly reduce food spoilage caused by seasonal changes and other factors.

  Therefore, PVDC high barrier film plays an important role in improving the packaging quality of enterprises.

 

  Comparison Chart of Oxygen Barrier between PVDC High Barrier Film and EVOH Coextruded Film

 Comparison Chart of Oxygen Barrier between PVDC High Barrier Film and EVOH Coextruded Film

 

  Comparison of Barrier Properties between PVDC High Barrier Film and Other Packaging Films

 

Polymer

Oxygen

Water Vapor

Carbon Dioxide

Nitrogen

PVDC (MA Copolymer)

0.5-6

0.1-0.3

0.1-0.5

0.1-0.5

PVDC (VC Copolymer)

43931

0.4-1.0

0.3-0.7

0.1-0.8

PA6

35

93-155

43-59

 

PP

300

3.6-10.2

1200

60

PET

74-138

27.4-46.7

35-50

44189

PVC

77-310

13.2-71.3

140-400

 

LDPE

500-700

15.2-23.4

2000-4000

200-400

HDPE

200-500

3.5-11.1

2000-4000

15-300

PS

600-800

10.5-33.6

2000-4000

40-50

PAN

11.6

31.0-47.2

6

 

EVOH

0.2

47

0.9

0.02

(32% Ethylene)

EVOH

1.8

95

1.4

0.13

(44% Ethylene)

 

  Note: Film thickness 25.4um; gas permeability unit cm³/m²*24h*0.1MPa, 50% RH; water vapor permeability unit: g/cm³*24h, 100% RH

 

  The table shows that PVDC has excellent barrier properties, exhibiting very high resistance to oxygen, nitrogen, carbon dioxide, and water vapor; compared to other materials, its barrier performance is several times or even hundreds of times better.

  The figure shows that the barrier performance of the PVDC high-barrier film does not change with variations in environmental humidity. Even in high humidity environments such as regions with high humidity and the southern rainy season, it still maintains its high barrier properties.

Keywords: Masterbatch

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